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Publications

Amorphization mechanism of SrIrO3electrocatalyst: How oxygen redox initiates ionic diffusion and structural reorganization

Cornell Affiliated Author(s)
Author
G. Wan
J.W. Freeland
J. Kloppenburg
G. Petretto
J.N. Nelson
D.-Y. Kuo
C.-J. Sun
J. Wen
J.T. Diulus
G.S. Herman
Y. Dong
R. Kou
J. Sun
S. Chen
K.M. Shen
D.G. Schlom
G.-M. Rignanese
G. Hautier
D.D. Fong
Z. Feng
H. Zhou
J. Suntivich
Abstract

The use of renewable electricity to prepare materials and fuels from abundant molecules offers a tantalizing opportunity to address concerns over energy and materials sustainability. The oxygen evolution reaction (OER) is integral to nearly all material and fuel electrosyntheses. However, very little is known about the structural evolution of the OER electrocatalyst, especially the amorphous layer that forms from the crystalline structure. Here, we investigate the interfacial transformation of the SrIrO3OER electrocatalyst.

Journal
Science Advances
Date Published
Group (Lab)
Kyle Shen Group

Strain-stabilized superconductivity

Cornell Affiliated Author(s)
Author
J.P. Ruf
H. Paik
N.J. Schreiber
H.P. Nair
L. Miao
J.K. Kawasaki
J.N. Nelson
B.D. Faeth
Y. Lee
B.H. Goodge
B. Pamuk
C.J. Fennie
L.F. Kourkoutis
D.G. Schlom
K.M. Shen
Abstract

Superconductivity is among the most fascinating and well-studied quantum states of matter. Despite over 100 years of research, a detailed understanding of how features of the normal-state electronic structure determine superconducting properties has remained elusive. For instance, the ability to deterministically enhance the superconducting transition temperature by design, rather than by serendipity, has been a long sought-after goal in condensed matter physics and materials science, but achieving this objective may require new tools, techniques and approaches.

Journal
Nature Communications
Date Published
Funding Source
DMR-1539918
DMR-1709255
DE-SC0019414
FA9550-15-1-0474
GBMF3850
GBMF9073
DMR-1719875
ECCS-1542081
Group (Lab)
Kyle Shen Group

Ab initio theory of the impact of grain boundaries and substitutional defects on superconducting Nb3Sn

Author
M.M. Kelley
N.S. Sitaraman
Tomas Arias
Abstract

Grain boundaries play a critical role in superconducting applications of Nb3Sn: in dc applications, grain boundaries preserve the material's inherently high critical current density by pinning flux, while in ac applications grain boundaries can provide weak points for flux entry leading to significant dissipation. We present the first ab initio study to investigate the physics of different grain boundary types in Nb3Sn and their impact on superconductivity using density-functional theory.

Journal
Superconductor Science and Technology
Date Published
Group (Lab)
Tomas Arias Group

Evolution of single gyroid photonic crystals in bird feathers

Cornell Affiliated Author(s)
Author
Vinodkumar Saranathan
Suresh Narayanan
Alec Sandy
Eric Dufresne
Richard Prum
Abstract

Vivid, saturated structural colors are conspicuous and important features of many animals. A rich diversity of three-dimensional periodic photonic nanostructures is found in the chitinaceous exoskeletons of invertebrates. Three-dimensional photonic nanostructures have been described in bird feathers, but they are typically quasi-ordered. Here, we report bicontinuous single gyroid β-keratin and air photonic crystal networks in the feather barbs of blue-winged leafbirds ( Chloropsis cochinchinensis sensu lato ), which have evolved from ancestral quasi-ordered channel-type nanostructures.

Journal
Proceedings of the National Academy of Sciences
Date Published
Funding Source
CRP20-2017-0004
R-607-265-241-121
DE-AC02-06CH11357
Research Area
Group (Lab)
Eric Dufresne Group

Microscale strain mapping demonstrates the importance of interface slope in the mechanics of cartilage repair

Cornell Affiliated Author(s)
Author
R.M. Irwin
T. Gao
A.J. Boys
K. Ortved
Itai Cohen
L.J. Bonassar
Abstract

Achieving lateral integration of articular cartilage repair tissue with surrounding native cartilage remains a clinical challenge. Histological and bulk mechanical studies have identified extracellular matrix components that correlate with superior failure strength, but it is unclear how local changes in geometry and composition at the repair interface affect tissue strains under physiologic loading.

Journal
Journal of Biomechanics
Date Published
Funding Source
P200A150273 J
1536463
DMR-1719875
F31AR070009
R01AR071394
Research Area
Group (Lab)
Itai Cohen Group

Superconductivity and quantum criticality linked by the Hall effect in a strange metal

Cornell Affiliated Author(s)
Author
Ian Hayes
Nikola Maksimovic
Gilbert Lopez
Mun Chan
B. Ramshaw
Ross McDonald
James Analytis
Abstract

Many unconventional superconductors exhibit a common set of anomalous charge transport properties that characterize them as ‘strange metals’, which provides hope that there is a single theory that describes them1–3. However, model-independent connections between the strange metals and superconductivity have remained elusive. Here, we show that the Hall effect of the unconventional superconductor BaFe2(As1−xPx)2 contains an anomalous contribution arising from the correlations within the strange metal.

Journal
Nature Physics
Date Published
Funding Source
DMR-1157490
DMR-1644779
GBMF9067
DE-AC02-05CH11231
Group (Lab)
Brad Ramshaw Group

Sustained enzymatic activity and flow in crowded protein droplets

Cornell Affiliated Author(s)
Author
Andrea Testa
Mirco Dindo
Aleksander Rebane
Babak Nasouri
Robert Style
Ramin Golestanian
Eric Dufresne
Paola Laurino
Abstract

Living cells harvest energy from their environments to drive the chemical processes that enable life. We introduce a minimal system that operates at similar protein concentrations, metabolic densities, and length scales as living cells. This approach takes advantage of the tendency of phase-separated protein droplets to strongly partition enzymes, while presenting minimal barriers to transport of small molecules across their interface.

Journal
Nature Communications
Date Published
Funding Source
GR19106
P19764
172824
Research Area
Group (Lab)
Eric Dufresne Group

Tuning layer-hybridized moiré excitons by the quantum-confined Stark effect

Cornell Affiliated Author(s)
Author
Y. Tang
J. Gu
S. Liu
K. Watanabe
T. Taniguchi
J. Hone
K.F. Mak
J. Shan
Abstract

Moiré superlattices offer an unprecedented opportunity for tailoring interactions between quantum particles1–11 and their coupling to electromagnetic fields12–18. Strong superlattice potentials generate moiré minibands of excitons16–18—bound pairs of electrons and holes that reside either in a single layer (intralayer excitons) or in two separate layers (interlayer excitons). Twist-angle-controlled interlayer electronic hybridization can also mix these two types of exciton to combine their strengths13,19,20.

Journal
Nature Nanotechnology
Date Published
Funding Source
FA9550-18-1-0480
DMR-2004451
W911NF-17-1-0605
DE-SC0019481
JPMJCR15F3
Group (Lab)
Jie Shan Group
Kin Fai Mak Group