Publications
Preparation of Macroscopic Block-Copolymer-Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation
Properties arising from ordered periodic mesostructures are often obscured by small, randomly oriented domains and grain boundaries. Bulk macroscopic single crystals with mesoscale periodicity are needed to establish fundamental structure–property correlations for materials ordered at this length scale (10–100 nm). A solvent-evaporation-induced crystallization method providing access to large (millimeter to centimeter) single-crystal mesostructures, specifically bicontinuous gyroids, in thick films (>100 µm) derived from block copolymers is reported.
Synergistic Coordination of Chromatin Torsional Mechanics and Topoisomerase Activity
The material properties of eukaryotic chromatin fibers partition supercoiling ahead of progressing replication forks, illustrating that chromatin provides a buffer against torsional stress and that its unique mechanical properties help to facilitate replication and minimize genome instability. © 2019 Elsevier Inc. DNA replication in eukaryotes generates DNA supercoiling, which may intertwine (braid) daughter chromatin fibers to form precatenanes, posing topological challenges during chromosome segregation. The mechanisms that limit precatenane formation remain unclear.
Electronic and vibrational signatures of ruthenium vacancies in Sr2RuO4 thin films
The synthesis of stoichiometric Sr2RuO4 thin films has been a challenge because of the high volatility of ruthenium oxide precursors, which gives rise to ruthenium vacancies in the films. Ru vacancies greatly affect the transport properties and electronic phase behavior of Sr2RuO4, but their direct detection is difficult due to their atomic dimensions and low concentration. We applied polarized X-ray absorption spectroscopy at the oxygen K edge and confocal Raman spectroscopy to Sr2RuO4 thin films synthesized under different conditions.
Probing and controlling magnetic states in 2D layered magnetic materials
The discovery of atomic monolayer magnetic materials has triggered significant interest in the magnetism/spintronics and 2D van der Waals materials communities. Here we review recent progress in this rapidly growing field. We survey the physical properties of the large class of layered magnetic materials, and discuss recent advances in the study of these materials in the 2D limit.
Using Acoustic Perturbations to Dynamically Tune Shear Thickening in Colloidal Suspensions
Colloidal suspensions in industrial processes often exhibit shear thickening that is difficult to control actively. Here, we use piezoelectric transducers to apply acoustic perturbations to dynamically tune the suspension viscosity in the shear-thickening regime. We attribute the mechanism of dethickening to the disruption of shear-induced force chains via perturbations that are large relative to the particle roughness scale.
Capillary Origami with Atomically Thin Membranes
Small-scale optical and mechanical components and machines require control over three-dimensional structure at the microscale. Inspired by the analogy between paper and two-dimensional materials, origami-style folding of atomically thin materials offers a promising approach for making microscale structures from the thinnest possible sheets. In this Letter, we show that a monolayer of molybdenum disulfide (MoS2) can be folded into three-dimensional shapes by a technique called capillary origami, in which the surface tension of a droplet drives the folding of a thin sheet.
Long valley lifetime of dark excitons in single-layer WSe2
Single-layer transition metal dichalcogenides provide a promising material system to explore the electron’s valley degree of freedom as a quantum information carrier. The valley degree of freedom can be directly accessed by means of optical excitation. However, rapid valley relaxation of optically excited electron-hole pairs (excitons) through the exchange interaction has been a major roadblock. Theoretically such valley relaxation is suppressed in dark excitons, suggesting a potential route for long valley lifetimes.
Using the Ecology and Evolution-Measuring Achievement and Progression in Science assessment to measure student thinking across the Four-Dimensional Ecology Education framework
The newly developed Four-Dimensional Ecology Education (4DEE) framework, produced by the Ecological Society of America, provides updated guidance for undergraduate instruction. To help instructors align their courses to this framework and assess student progress toward its goals, we have recoded the comprehensive programmatic assessment Ecology and Evolution-Measuring Achievement and Progression in Science (EcoEvo-MAPS) and reanalyzed a national dataset of over 2000 undergraduate student responses.
Optical signatures of the chiral anomaly in mirror-symmetric Weyl semimetals
The chiral anomaly is a characteristic phenomenon of Weyl fermions, which has condensed matter realizations in Weyl semimetals. Efforts to observe smoking gun signatures of the chiral anomaly in Weyl semimetals have mostly focused on a negative longitudinal magnetoresistance in electronic transport. Unfortunately, disentangling the chiral anomaly contribution in transport or optical measurements has proven nontrivial. Recent works have proposed an alternative approach of probing pseudoscalar phonon dynamics for signatures of the chiral anomaly in non-mirror-symmetric crystals.
Density matrix renormalization group study of superconductivity in the triangular lattice Hubbard model
With the discovery of strong-coupling physics and superconductivity in moiré superlattices, it is essential to have an understanding of strong-coupling driven superconductivity in systems with trigonal symmetry. The simplest lattice model with trigonal symmetry is the triangular lattice Hubbard model. Although the triangular lattice spin model is a heavily studied model in the context of frustration, studies of the hole-doped triangular lattice Hubbard model are rare.