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The generalized Clapeyron equation and its application to confined ice growth

Cornell Affiliated Author(s)

Author

R.W. Style
D. Gerber
A.W. Rempel
E.R. Dufresne

Abstract

Most theoretical descriptions of stresses induced by freezing are rooted in the (generalized) Clapeyron equation, which predicts the pressure that a solid can exert as it cools below its melting temperature. This equation is central for topics ranging beyond glaciology to geomorphology, civil engineering, food storage and cryopreservation. However, it has inherent limitations, requiring isotropic solid stresses and conditions near bulk equilibrium. Here, we examine when the Clapeyron equation is applicable by providing a rigorous derivation that details all assumptions. We demonstrate the natural extension for anisotropic stress states, and we show how the temperature and pressure ranges for validity depend on well-defined material properties. Finally, we demonstrate how the range of applicability of the (linear) Clapeyron equation can be extended by adding higher-order terms, yielding results that are in good agreement with experimental data for the pressure melting of ice. Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of The International Glaciological Society.

Date Published

Journal

Journal of Glaciology

Volume

514

Issue

7520

Number of Pages

1-6,

ISBN Number

00221430 (ISSN)

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160556942&doi=10.1017%2fjog.2023.28&partnerID=40&md5=66ca4a89d60a46f50dd9654e5fd7e17a

DOI

10.1017/jog.2023.28

Alternate Journal

J. Glaciol.

Group (Lab)

Eric Dufresne Group

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