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Absence of 3a 0 charge density wave order in the infinite-layer nickelate NdNiO2

Cornell Affiliated Author(s)

Author

C.T. Parzyck
N.K. Gupta
Y. Wu
V. Anil
L. Bhatt
M. Bouliane
R. Gong
B.Z. Gregory
A. Luo
R. Sutarto
F. He
Y.-D. Chuang
T. Zhou
G. Herranz
L.F. Kourkoutis
A. Singer
D.G. Schlom
D.G. Hawthorn
K.M. Shen

Abstract

A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a 0 charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO2+x samples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO2. The 3a 0 superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO2 highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors. © 2024, The Author(s).

Date Published

Journal

Nature Materials

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85183190406&doi=10.1038%2fs41563-024-01797-0&partnerID=40&md5=b441e9ed37a0dce753a6befec00ba861

DOI

10.1038/s41563-024-01797-0

Group (Lab)

Kyle Shen Group

Funding Source

CEX2019-000917-S
DMR-1719875
DMR-2039380
DMR-2104427
NNCI-2025233
FA9550-21-1-0168
GBMF3850
GBMF9073
DE-AC02-05CH11231
DE-SC0019414
DE-AC02-06CH11357
2021 SGR 00445

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